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RARE EARTHS
by Jonathan Buhalis

History

Rare earths are a set of related metals close together on the Periodic Table of the Elements. Most are clustered in the lanthanide series (the * in the table at the bottom), plus scandium and yttrium just above them.

The story of the rare earths starts in 1787, when swedish chemist Carl Axel Arrhenius picked up a black mineral he called "ytterbite" from a quarry in the village of Ytterby, Sweden. Over the next sixty years, various chemical separation techniques teased several new elements out of the mineral. In consequence, we have a number of elements (yttrium, ytterbium, erbium, terbium) all named after one small Swedish settlement.

Meanwhile, chemists Jöns Jacob Berzelius and Wilhelm Hisinger in 1803 produced an oxide of what would prove to be the rare earth element cerium. That oxide, ceria, was later found to contain other rare earth elements, including lanthanum.

The lightest of the rare earths, scandium, was discovered in parallel. The creator of the periodic table, Russian Dmitri Mendeleev, had in 1869 predicted the existence of an element below boron. A team at the university in Uppsala, Sweden, led by Lars Fredrik Nilson found this element in 1879 when examining his own sample of ytterbite. He named it scandium after Scandinavia. Although we arrange the periodic table differently now, scandium had the predicted properties.

The use of spectroscopy in the late 19th century revealed other trace elements in both ytterbite and ceria. The eventual number of rare earths would be 17.

Element 61, promethium, is a curiosity. When Henry Moseley in 1914 determined the atomic number of elements, he saw that there was no element 61. In fact, all forms of this element are radioactive and unstable with very short half-lives. The element was actually created synthetically in 1945 at the Oak Ridge National Laboratory. The new element, named promethium after the god Promethius, was one of the decay products of uranium fission. Even now, promethium is created by nuclear reactions and not mined.

Mining and Production

Rare earth metals are not called rare for their scarcity in the Earth's crust(cerium, at least, is moderately common), but because they tend not to occur in concentrated ore bodies. They are also chemically very similar and notoriously hard to separate. Any ore that contains one of the rare earths also contains many others.

Consistent with their history, rare earths tend to occur together in two groups, one with cerium and one with yttrium. The cerium elements are mined in small amounts around the world. The yttrium elements are mined primarily in China, a country not known for generous exports. New applications of these metals may easily become frustrated by lack of supply.

Properties and Uses

Obvious chemistry notwithstanding, the rare earths have highly specific uses in which their performance justifies the cost.

neodymium magnets, (c) Nevit Dilmen; A. Jonathan Buhalis

Clean tech uses of the rare earths include lasers and magnets (the powerful so-called "rare earth magnets"). These magnets may be found in wind turbine engines, for example, where they help to generate clean energy. The most powerful laboratory magnets will use holmium. Much more numerous are the magnets in computer hard drives containing neodymium, dysprosium, or terbium.

The (nickel-metal hydride) batteries and regenerative braking of electric cars use trace rare earths. For fossil-fuel cars, cerium and lanthanum are alternatives to platinum as the catalyst in catalytic converters.

pulsed Nd-YAG laser, A. Jonathan Buhalis

Yttrium, europium, and others are used in lasers, such as this one using neodymium-doped yttrium aluminum garnet crystal. Yttrium is used in red LEDs and in the red phosphors of CRT monitors.

Gadolinium is valuable for use in computer memory chips and other high-tech components. Relatively abundant cerium produces a yellow color in glass and ceramics.

Scandium is primarily used as a minor alloy with aluminum. The scandium prevents large aluminum crystal forming, which can create weaknesses in the metal. Scandium aluminum is sometimes used in aircraft and also in sports equipment, similar to titanium.

The Periodic Table of Elements, A. Jonathan Buhalis
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Content by Jonathan Buhalis
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